When the concentration of $A$ in the reaction $A + B \rightleftharpoons AB$ is doubled,the rate of reaction will be

  • A
    Doubled
  • B
    Decreased by half
  • C
    Unchanged
  • D
    Increased by four times

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The following results have been obtained during the kinetic studies of the reaction:
$2 A + B \rightarrow C + D$
Experiment $[A] / mol \, L^{-1}$ $[B] / mol \, L^{-1}$ Initial rate of formation of $D / mol \, L^{-1} \, min^{-1}$
$I$ $0.1$ $0.1$ $6.0 \times 10^{-3}$
$II$ $0.3$ $0.2$ $7.2 \times 10^{-2}$
$III$ $0.3$ $0.4$ $2.88 \times 10^{-1}$
$IV$ $0.4$ $0.1$ $2.40 \times 10^{-2}$

Determine the rate law and the rate constant for the reaction.

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The following are the rate constants of two different reactions. What is the overall order of each reaction?
$(a)$ $2.1 \times 10^{-2} \ mol \ L^{-1} \ s^{-1}$
$(b)$ $4.5 \times 10^{-3} \ min^{-1}$

For the reaction between $A$ and $B$,the initial rate of reaction $(r_0)$ was measured for different initial concentrations of $A$ and $B$ as given below. Determine the order of the reaction with respect to $A$ and $B$ respectively.
$[A] / mol \ L^{-1}$$0.2, 0.2, 0.4$
$[B] / mol \ L^{-1}$$0.3, 0.1, 0.05$
$r_0 / mol \ L^{-1} s^{-1}$$5.0 \times 10^{-5}, 5.0 \times 10^{-5}, 1.4 \times 10^{-4}$

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For the reaction $A + B \to C$,it is found that doubling the concentration of $A$ increases the rate by $4$ times,and doubling the concentration of $B$ doubles the reaction rate. What is the overall order of the reaction?

For the reaction $2H_2 + 2NO \to N_2 + 2H_2O$,the following mechanism has been proposed:
$I$. $2NO \rightleftharpoons N_2O_2$ (fast)
$II$. $N_2O_2 + H_2 \xrightarrow{k_2} N_2O + H_2O$ (slow)
$III$. $N_2O + H_2 \to N_2 + H_2O$ (fast)
What will be the rate law of this reaction?

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